Published in
Wiley-VCH Verlag, ChemInform, 1(35), 2004
Elsevier, Tetrahedron Letters, 39(44), p. 7359-7363
DOI: 10.1016/s0040-4039(03)01844-6
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A New Method for the Synthesis of Bishydroperoxides Based on a Reaction of Ketals with Hydrogen Peroxide Catalyzed by Boron Trifluoride Complexes.
Journal article published in 2003 by
Alexander O. Terent'ev 
,
Alexander V. Kutkin,
Maxim M. Platonov,
Yuri N. Ogibin,
Gennady I. Nikishin
,
Alexander V. Kutkin,
Maxim M. Platonov,
Yuri N. Ogibin,
Gennady I. Nikishin
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Abstract
A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H2O2 catalyzed by boron trifluoride etherate and boron trifluoride–methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1′-dihydroperoxyperoxides and 1,2,4,5-tetraoxacyclohexanes, was developed based on this reaction.