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Elsevier, Water Research, 14(37), p. 3390-3400, 2003

DOI: 10.1016/s0043-1354(03)00231-8

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Phosphorus adsorption maximum of sands for use as media in subsurface flow constructed reed beds as measured by the Langmuir isotherm

Journal article published in 2003 by M. Del Bubba, C. A. Arias, H. Brix ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The P-adsorption capacities of 13 Danish sands were studied by short-term isotherm batch experiments and related to the physico-chemical characteristics of the sands. The maximum P-adsorption capacities (Q) and P-binding energy constants (b) were calculated using the Langmuir-isotherm model. The Freundlich model was also used, but it was not useful for the description of adsorption phenomena per se since it fitted well P-removal data even if precipitation of P-salts occurred simultaneously. The Langmuir model described the data well (R(2)=0.90-0.99) when precipitation of phosphates did not occur and seems therefore to be useful for describing the adsorption processes per se. The relationships between maximum sorption capacities and physico-chemical characteristics of the sands were investigated using classical univariate and partial least squares regression analyses. Among the physico-chemical properties of the sands, Ca and Mg content, grain size, porosity, bulk density and hydraulic conductivity were significantly related (P<0.1) to the maximum adsorption capacity as estimated by the Langmuir model. Using the maximum P-adsorption capacities, it was estimated how long the P-removal can be sustained with the different sands in subsurface flow constructed reed beds. If the most efficient sand for P-adsorption was used, the adsorption capacity would be used up after about 1 year, while, for the less efficient sands, the P-retention would go on for about 2 months. This suggests that, in order to sustain a long-term P-removal in subsurface flow constructed reed beds, precipitation reactions of insoluble P-salts should be promoted. P-binding energy constants were not significantly related to the physico-chemical properties of the sands, except the Ca content, which showed, however, a low correlation coefficient.