Dissemin is shutting down on January 1st, 2025

Published in

Elsevier, Chemical Engineering Science, 24(49), p. 5377-5390

DOI: 10.1016/0009-2509(94)00332-7

Links

Tools

Export citation

Search in Google Scholar

Methanol to olefins—prediction of the performance of a circulating fluidized-bed reactor on the basis of kinetic experiments in a fixed-bed reactor

Journal article published in 1994 by Hendrik Schoenfelder, Juergen Hinderer, Joachim Werther, Frerich J. Keil
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The conversion of methanol to olefins (MTO) over a zeolite catalyst is used as an example for the investigation of a circulating fluidized bed (CFB) reactor/regenerator system. A lumped-species reaction scheme has been developed which accounts for the most relevant components. Kinetic experiments were carried out in a standard fixed-bed Berty reactor over the 400°C to 500°C range at atmospheric pressure. The MTO process was performed in a circulating fluidized bed (riser dimensions: internal diameter 0.03 m, height 11 m) that is coupled with a regenerator for continuously burning off the coke deposits. Conversion of more than 98% and a very high olefin selectivity have been achieved. Based on the estimated kinetic parameters and on a CFB reactor model, methanol conversion and product distribution is predicted and compared with experimental data. The agreement is satisfactory for the whole temperature range examined.