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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 11(66), p. m1417-m1418, 2010

DOI: 10.1107/s1600536810040791

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1-(Diphenylphosphinothioyl)-2-[(4-methylphenyl)methoxymethyl]ferrocene

Journal article published in 2010 by Jean-Claude Daran, Catherine Audin, Eric Deydier, Eric Manoury, Rinaldo Poli ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Following our continuing inter-est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol-ecules in the asymmetric unit. The conformation of the cyclo-penta-dienyl (Cp) rings in each ferrocenyl group are inter-mediate between eclipsed and staggered, with twist angles of 16.6 (2) and 8.9 (2)°. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, mol-ecules are connected through inter-molecular C-H⋯π inter-actions.