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Published in

Elsevier, Journal of Magnetism and Magnetic Materials, (272-276), p. 468-469

DOI: 10.1016/j.jmmm.2003.11.190

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On the structure and magnetic properties of CeNi with minor Cu substitutions

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The introduction of Cu in the CeNi compound maintains the same crystallographic CrB-type structure up to CeNi0.85Cu0.15. The crystallographic structure of several compositions in the neighbourhood of this limit has been determined from single crystals in a 4-circle diffractometer. The thermal expansion coefficients of CeNi0.9Cu0.1 behave similar to those of CeNi. The Cu substitution disturbs the intermediate valence behaviour of CeNi, inducing non-zero magnetic moments at low temperatures and suggesting a cluster-glass behaviour.