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Royal Society of Chemistry, Chemical Communications, 69(48), p. 8691, 2012

DOI: 10.1039/c2cc33446a

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Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(I)-silver(I) clusters

Journal article published in 2012 by Li-Qin Mo, 王泉明, Jian-Hua Jia ORCID, Li-Jia Sun, Quan-Ming Wang
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Blue or yellow-green emission is observed from two different crystal types of the same gold(I)-silver(I) molecular cluster [SAu3Ag(L1)(3)](BF4)(2) (L1 = 2-diphenylphosphino-4-methylpyridine) depending on the crystallization conditions; structural data suggest that intermolecular Au center dot center dot center dot Au interactions account for the luminescence vapochromic responses; a similar observation was made on two other pairs of analogues. ; Natural Science Foundation of China [21125102, 20973135, 90922011, 21021061]