Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 44(14), p. 15278, 2012
DOI: 10.1039/c2cp42451g
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Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex
Journal article published in 2012 by
Claudio Garino,
Erik Gallo,
Nikolay Smolentsev,
Pieter Glatzel,
Roberto Gobetto,
Carlo Lamberti 
,
Peter J. Sadler,
Peter J. Sadlerd,
Luca Salassa
,
Peter J. Sadler,
Peter J. Sadlerd,
Luca Salassa
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Abstract
Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy. © 2012 the Owner Societies.