Published in
Royal Society of Chemistry, Dalton Transactions, 32(43), p. 12146-12149, 2014
DOI: 10.1039/c4dt00846d
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Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes
Journal article published in 2014 by
Luke J. Batchelor,
Irene Cimatti,
Régis Guillot,
Floriana Tuna,
Wolfgang Wernsdorfer,
Liviu Ungur 
,
Liviu F. Chibotaru ,
Victoria E. Campbell,
Talal Mallah,
I. Cimatti R Guillot F Tuna W Wernsdorfer L Ungur L F. Chibotaru V E. Campbell T Mallah L. J. Batchelor
,
Liviu F. Chibotaru ,
Victoria E. Campbell,
Talal Mallah,
I. Cimatti R Guillot F Tuna W Wernsdorfer L Ungur L F. Chibotaru V E. Campbell T Mallah L. J. Batchelor
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Abstract
A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations.