Published in
Royal Society of Chemistry, Chemical Science, 32(14), p. 8662-8671, 2023
DOI: 10.1039/d3sc03095d
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“Mn-locking” effect by anionic coordination manipulation stabilizing Mn-rich phosphate cathodes
Journal article published in 2023 by
Wei Zhang 
,
Yulun Wu,
Yuhang Dai ,
Zhenming Xu ,
Liang He,
Zheng Li,
Shihao Li,
Ruwei Chen,
Xuan Gao,
Wei Zong ,
Fei Guo,
Jiexin Zhu,
Haobo Dong,
Jianwei Li,
Chumei Ye
and other authors.
,
Yulun Wu,
Yuhang Dai ,
Zhenming Xu ,
Liang He,
Zheng Li,
Shihao Li,
Ruwei Chen,
Xuan Gao,
Wei Zong ,
Fei Guo,
Jiexin Zhu,
Haobo Dong,
Jianwei Li,
Chumei Ye
and other authors.
This paper is made freely available by the publisher.
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Abstract
Our study introduced light-weight fluorine into Mn-rich cathode to trigger a “Mn-locking” effect: more robust Mn ligand framework, suppressed Mn dissolution, improved structural stability and enhanced electronic conductivity.