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Published in

IOP Publishing, Journal of Physics: Condensed Matter, 24(33), p. 245802, 2021

DOI: 10.1088/1361-648x/abf594

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Magnetic ordering in the Ising antiferromagnetic pyrochlore Nd<sub>2</sub>ScNbO<sub>7</sub>

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Abstract The question of structural disorder and its effects on magnetism is relevant to a number of spin liquid candidate materials. Although commonly thought of as a route to spin glass behaviour, here we describe a system in which the structural disorder results in long-range antiferromagnetic order due to local symmetry breaking. Nd2ScNbO7 is shown to have a dispersionless gapped excitation observed in other neodymium pyrochlores below T N = 0.37 K through polarized and inelastic neutron scattering. However the dispersing spin waves are not observed. This excited mode is shown to occur in only 14(2)% of the neodymium ions through spectroscopy and is consistent with total scattering measurements as well as the magnitude of the dynamic moment 0.26(2) μ B . The remaining magnetic species order completely into the all-in all-out Ising antiferromagnetic structure. This can be seen as a result of local symmetry breaking due disordered Sc+3 and Nb+5 ions about the A-site. From this work, it has been established that B-site disorder restores the dipole-like behaviour of the Nd+3 ions compared to the Nd2B2O7 parent series.