Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 12(11), p. 6198-6204, 2023
DOI: 10.1039/d3ta00436h
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The importance of lone pairs to structure and bonding of the novel germanium nitridophosphate GeP<sub>2</sub>N<sub>4</sub>
Journal article published in 2023 by
Tristan de Boer 
,
Cody Somers,
Teak Boyko ,
Sebastian Ambach,
Lucien Eisenburger,
Wolfgang Schnick ,
Alexander Moewes
,
Cody Somers,
Teak Boyko ,
Sebastian Ambach,
Lucien Eisenburger,
Wolfgang Schnick ,
Alexander Moewes
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Abstract
The new nitridophosphate GeP2N4 differs structurally from all other known MP2N4 phases, owing to a Ge2+ lone pair. Its stereochemical influence could be exploited to tune the properties of other compounds when M2+ is exchanged with Ge2+.