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Royal Society of Chemistry, Chemical Science, 18(13), p. 5268-5276, 2022

DOI: 10.1039/d2sc01244h

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Unmasking the constitution and bonding of the proposed lithium nickelate “Li<sub>3</sub>NiPh<sub>3</sub>(solv)<sub>3</sub>”: revealing the hidden C<sub>6</sub>H<sub>4</sub>ligand

Journal article published in 2022 by Rosie J. Somerville ORCID, Andryj M. Borys ORCID, Marina Perez-Jimenez ORCID, Ainara Nova ORCID, David Balcells ORCID, Lorraine A. Malaspina ORCID, Simon Grabowsky ORCID, Ernesto Carmona ORCID, Eva Hevia ORCID, Jesús Campos ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We disclose the actual octanuclear nature of the major compound from reacting Ni(COD)2and PhLi, assigned for more than four decades as ‘Li3NiPh3(solv)3’. We provide a thorough bonding analysis and discuss its potential implications in catalysis.