Thieme Gruppe, Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 02(33), p. 177-181, 2021
DOI: 10.1055/a-1691-0449
Full text: Unavailable
AbstractEfficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range of nitrones in high yields under mild conditions. In addition, an oxidative (3+3) cycloaddition between an oxyallyl cation precursor and a hydroxylamine was also developed.