Published in

American Association for the Advancement of Science, Science, 6576(375), p. 62-66, 2022

DOI: 10.1126/science.abg3793

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Single-walled zeolitic nanotubes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Zeolitic nanotubes Nanotubes generally have solid walls, but a low-dimensional version of zeolites now introduces porosity into such structures. Korde et al . used a structure-directing agent with a hydrophobic biphenyl group center connecting two long alkyl chains bearing hydrophilic bulky quaternary ammonium head groups to direct hydrothermal synthesis with silicon-rich precursors (see the Perspective by Fan and Dong). The nanotubes have a mesoporous central channel of approximately 3 nanometers and zeolitic walls with micropores less than 0.6 nanometers. Electron microscopy and modeling showed that the outer surface is a projection of a large-pore zeolite and the inner surface is a projection of a medium-pore zeolite. —PDS