Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 6(8), p. 1610-1618, 2021
DOI: 10.1039/d0qi01368d
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Acid-triggering of light-induced charge-separation in hybrid organic/inorganic molecular photoactive dyads for harnessing solar energy
Journal article published in 2021 by
Elisabetta Benazzi,
Joshua Karlsson,
Youssef Ben M'Barek,
Youssef Ben M'Barek,
Pavel Chabera 
,
Sébastien Blanchard,
Sandra Alves,
Anna Proust ,
Tönu Pullerits ,
Guillaume Izzet ,
Elizabeth A. Gibson
,
Sébastien Blanchard,
Sandra Alves,
Anna Proust ,
Tönu Pullerits ,
Guillaume Izzet ,
Elizabeth A. Gibson
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Abstract
H+ modulated charge-transfer in photoexcited covalently linked W and Mo Keggin-bodipy conjugates is demonstrated using transient absorption spectroscopy and photoluminescence. Adding acid switches on (W) or accelerates (Mo) charge separation.