Published in
Royal Society of Chemistry, Dalton Transactions, 38(49), p. 13386-13392, 2020
DOI: 10.1039/d0dt02797a
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An Intermolecular FLP System derived from an NHC-coordinated Trisilacyclopropylidene
Journal article published in 2020 by
Benedikt J. Guddorf,
Alexander Hepp 
,
Constantin Gabriel Daniliuc ,
Douglas W. Stephan ,
Felicitas Lips
,
Constantin Gabriel Daniliuc ,
Douglas W. Stephan ,
Felicitas Lips
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Abstract
An intermolecular FLP system with an NHC-coordinated trisilacyclopropylidene acting as the Lewis base is shown to split dihydrogen heterolytically under ambient conditions, and reacts with Ph2NH, Me2CO, and N2O.