Published in

International Union of Crystallography, IUCrJ, 5(7), p. 913-919, 2020

DOI: 10.1107/s2052252520011021

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Charge density waves and degenerate modes in exfoliated monolayer 2H-TaS2

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Charge density waves spontaneously breaking lattice symmetry through periodic lattice distortion, and electron–electron and electron–phonon interactions, can lead to a new type of electronic band structure. Bulk 2H-TaS2 is an archetypal transition metal dichalcogenide supporting charge density waves with a phase transition at 75 K. Here, it is shown that charge density waves can exist in exfoliated monolayer 2H-TaS2 and the transition temperature can reach 140 K, which is much higher than that in the bulk. The degenerate breathing and wiggle modes of 2H-TaS2 originating from the periodic lattice distortion are probed by optical methods. The results open an avenue to investigating charge density wave phases in two-dimensional transition metal dichalcogenides and will be helpful for understanding and designing devices based on charge density waves.