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Published in

Nature Research, Scientific Reports, 1(10), 2020

DOI: 10.1038/s41598-020-58057-9

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Thickness-induced metal to insulator transition in Ru nanosheets probed by photoemission spectroscopy: Effects of disorder and Coulomb interaction

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

AbstractWe investigated the electronic structures of mono- and few-layered Ru nanosheets (N layers (L) with N = 1, ~6, and ~9) on Si substrate by ultra-violet and x-ray photoemission spectroscopies. The spectral density of states (DOS) near EF of ~6 L and 1 L is suppressed as it approaches EF in contrast to that of ~9 L, which is consistent with the Ru 3 d core-level shift indicating the reduction of the metallic conductivity. A power law g(ε) ∝ |ε − εF|α well reproduces the observed spectral DOS of ~6 L and 1 L. The evolution of the power factor α suggests that the transition from the metallic state of ~9 L to the 2-dimensional insulating state with the soft Coulomb gap of 1 L through the disordered 3-dimensional metallic state of ~6 L.