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Royal Society of Chemistry, Chemical Science, 32(10), p. 7496-7502, 2019

DOI: 10.1039/c9sc02274k

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Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Spin-crossover (SCO) system integrated with photochemical [2 + 2] reaction is firstly reported. The dimerization of azastilbene ligands dramatically modulated SCO properties, providing a new strategy for exploiting photo-responsive SCO materials.