Published in
Springer (part of Springer Nature), Catalysis Letters, 3(141), p. 370-373
DOI: 10.1007/s10562-010-0477-y
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Universal Bronsted-Evans-Polanyi Relations for C-C, C-O, C-N, N-O, N-N, and O-O Dissociation Reactions
Journal article published in 2010 by
Burcin Temel,
Shengguang Wang,
Juan Shen,
Glenn Jones,
Lars C. Grabow,
Felix Studt,
Thomas Bligaard,
Frank Abild-Pedersen,
Claus H. Christensen,
Jens K. Nørskov
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Abstract
It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.