Published in

International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 11(67), p. m1534-m1534, 2011

DOI: 10.1107/s1600536811041936

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μ4-Orthothio­carbonato-tetra­kis­[tri­carbonyl­iron(I)](2 Fe—Fe)

Journal article published in 2011 by Yao-Cheng Shi, Huan-Ren Cheng, Li-Min Yuan, Qian-Kun Li
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The fused bis-butterfly-shaped title compound, [Fe4(CS4)(CO)12], possesses an orthothio­carbonate (CS4 4−) ligand that acts as a bridge between two Fe2(CO)6 units. A short intra­molecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S2Fe2(CO)6 fragment.