International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 11(67), p. m1534-m1534, 2011
DOI: 10.1107/s1600536811041936
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The fused bis-butterfly-shaped title compound, [Fe4(CS4)(CO)12], possesses an orthothiocarbonate (CS4 4−) ligand that acts as a bridge between two Fe2(CO)6 units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S2Fe2(CO)6 fragment.