Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics
DOI: 10.1039/c8cp05332d
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Unimolecular Decomposition Kinetics of the Stabilised Criegee Intermediates CH2OO and CD2OO
Journal article published in 2018 by
Daniel Stone 
,
Kendrew Au,
Samantha Sime,
Diogo J. Medeiros ,
Mark Blitz ,
Paul W. Seakins ,
Zachary Decker ,
Leonid Sheps
,
Kendrew Au,
Samantha Sime,
Diogo J. Medeiros ,
Mark Blitz ,
Paul W. Seakins ,
Zachary Decker ,
Leonid Sheps
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Abstract
Decomposition kinetics of stabilised CH2OO and CD2OO Criegee intermediates have been investigated as a function of temperature (450–650 K) and pressure (2–350 Torr) using flash photolysis coupled with time-resolved cavity-enhanced broadband UV absorption spectroscopy.