Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 27(4), p. 6510-6515
DOI: 10.1039/c6tc01610c
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Fluorescence enhancement in crystals tuned by a molecular torsion angle: a model to analyze structural impact
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Abstract
Alkyl group substitutions induce a systematic tuning of an intramolecular torsion angle and supramolecular organization resulting in a parallel increase in the fluorescence enhancement (solution to crystal) factor. A model is developed to probe the molecular and crystal structural impact on fluorescence enhancement, and provide a basis for rational design.