Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 44(14), p. 10427-10436
DOI: 10.1039/c6ob01989g
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An MEDT study of the carbenoid-type [3 + 2] cycloaddition reactions of nitrile ylides with electron-deficient chiral oxazolidinones
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Abstract
A combination of the bonding evolution theory and non-covalent interactions analyses of TSs makes it possible to characterise both the carbenoid-type 32CA reaction between a NY and a chiral oxazolidinone, and the diastereoselectivity experimentally observed.