Published in
Royal Society of Chemistry, Dalton Transactions, 44(46), p. 15190-15194
DOI: 10.1039/c7dt03565a
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Catalyst free boron carbon bond cleavage and facile formation of five-membered PNBCC heterocycles
Journal article published in 2017 by
Rajarshi Dasgupta,
Atanu Panda,
Shiv Pal,
Puthan Veetil Muhasina,
Susmita De 
,
Pattiyil Parameswaran ,
Shabana Khan
,
Pattiyil Parameswaran ,
Shabana Khan
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Abstract
The [3 + 2] cycloaddition reaction of N(2,6-iPr2C6H3)(PPh2)(BCy2) (1) with activated alkynes led to the boron, phosphorus containing five-membered heterocycles (2–4) with facile cleavage of B–C bond and concomitant formation of a P–C bond with an ylidic character.