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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 13(19), p. 8989-8999
DOI: 10.1039/c7cp00809k
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High level potential energy surface and mechanism of Al(CH3)2OCH3-promoted lactone polymerization: initiation and propagation
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Abstract
A hitherto unreported, second transition state (TS2) is the stationary state with the highest relative energy of the Al(CH3)2OCH3 + glycolide initiation reaction.