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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 8(66), p. m899-m900, 2010

DOI: 10.1107/s1600536810026127

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Di-μ-chlorido-bis{chlorido[(R)/(S)-1,5-diphenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN2]zinc(II)}

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the centrosymmetric binuclear title compound, [Zn(2)Cl(4)(C(20)H(17)N(3))(2)], the coordination geometry of the Zn(II) ion can be described as a distorted ZnN(2)Cl(3) trigonal bipyramid (τ = 0.89), arising from the N,N'-bidentate ligand, a terminal chloride ion and two bridging chloride ions. The N atoms occupy one axial and one equatorial site and the terminal chloride ion occupies an equatorial site. The dihedral angle between the pyridine and pyrazole rings is 12.8 (2)°. In the crystal, aromatic π-π stacking [centroid-centroid separations = 3.812 (3) and 3.848 (3) Å] and C-H⋯Cl and C-H⋯π inter-actions help to establish the packing.