Published in
Royal Society of Chemistry, New Journal of Chemistry, 19(41), p. 10890-10898, 2017
DOI: 10.1039/c7nj02919e
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Three novel mononuclear Mn(iii)-based magnetic materials with square pyramidal versus octahedral geometries
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Abstract
Single crystal X-ray diffraction studies reveal that complexes 1 and 2 have square pyramidal geometry and 3 has octahedral geometry, which showed a dependence of negative anisotropy (D) values on the electronic, geometry and packing effects.