Published in
Royal Society of Chemistry, Catalysis Science & Technology, 12(2), p. 2453, 2012
DOI: 10.1039/c2cy20539d
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Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts
Journal article published in 2012 by
Anthony Garron,
François Stoffelbach,
Nicolas Merle,
Kaï Chung Szeto,
Jean Thivolle-Cazat,
Jean-Marie Basset 
,
Sébastien Norsic,
Mostafa Taoufik
,
Sébastien Norsic,
Mostafa Taoufik
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Abstract
2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.