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Oldenbourg Verlag, Radiochimica Acta, 12(95), p. 677-682, 2007

DOI: 10.1524/ract.2007.95.12.677

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Neptunium(V) disproportionation and cation–cation interactions in TBP/kerosene solvent

Journal article published in 2007 by Mark J. Sarsfield, Robin J. Taylor ORCID, Chris J. Maher
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Summary In 30% TBP/OK Np(V) is unstable and disproportionates to Np(IV) and Np(VI). Np(V) readily coordinates to Np(IV) in solution to form a “cation–cation” complex by bonding through an axial oxo group on Np(V). The rate of disproportionation in 30% TBP/OK is >500 times that in aqueous solution.