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Royal Society of Chemistry, Chemical Communications, 87(52), p. 12905-12908, 2016

DOI: 10.1039/c6cc05473k

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Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2-

Journal article published in 2016 by Xiaowen Feng, Jun-Liang Liu ORCID, Kasper S. Pedersen ORCID, Joscha Nehrkorn, Alexander Schnegg, Karsten Holldack, Jesper Bendix, Marc Sigrist, Hannu Mutka, Dumitru Samohvalov, David Aguila, Ming-Liang Tong ORCID, Jeffrey R. Long, Rodolphe Clérac
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This paper is available in a repository.

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Abstract

The mononuclear complex (Bu4N)2[ReIVCl4(CN)2].2DMA (DMA =N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency domain THz EPR investigations.