Royal Society of Chemistry, RSC Advances, 70(6), p. 66197-66203
DOI: 10.1039/c6ra08629b
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Engineering the surface structure of nanomaterials is of great importance for applications in energy conversion and storage. Herein, unique rutile TiO 2 nanoparticles have been successfully synthesized by a facile solution and subsequent thermal annealing method. Each particle surface has been etched to form pits with an average size of 2-5 nm, producing abundant steps and vacancies. When evaluated as anode materials for lithium-ion batteries, the yielded rutile TiO 2 nanoparticle electrode exhibits a maximum specific capacity of ∼145 mA h g -1 at a current density of 0.5C (1C = 335 A g -1 ) with outstanding charge/discharge rate capability (∼102 mA h g -1 at 5C) and good cycling performance.