Published in

Wiley, Angewandte Chemie, 29(128), p. 8498-8502, 2016

DOI: 10.1002/ange.201602909

Links

Tools

Export citation

Search in Google Scholar

Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates

Journal article published in 2016 by Pengpeng Liu, Yutaka Hisamune, Martin D. Peeks, Barbara Odell, Jq Gong, Lm Herz ORCID, Hl Anderson ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne-linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five-porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence extends to 1200 nm, reflecting strong π conjugation and Herzberg-Teller vibronic coupling.