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Royal Society of Chemistry, Chemical Communications, 65(49), p. 7201, 2013

DOI: 10.1039/c3cc44312d

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Accelerating influence of the gem-difluoromethylene group in a ring-closing olefin metathesis reaction. A Thorpe–Ingold effect?

Journal article published in 2013 by César Alejandro Urbina-Blanco, Maciej Skibiński, David O'Hagan, Steven P. Nolan ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The gem-difluoromethylene (CF2) group significantly accelerates ring-closing metathesis of 1,8-nonadienes relative to the methylene (CH2) group demonstrating similar rate accelerations to that observed for the classic Thorpe-Ingold substituents, diester malonates and ketals.