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International Union of Crystallography, Acta Crystallographica Section E: Crystallographic Communications, 12(71), p. o1015-o1016, 2015

DOI: 10.1107/s2056989015022872

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Crystal structure of (tert-butyldimethylsilyl)triphenylgermane, Ph3Ge-SiMe2(t-Bu)

Journal article published in 2015 by Kirill V. Zaitsev ORCID, Galina S. Zaitseva, Sergey S. Karlov, Alexander A. Korlyukov
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetrahedral coordination environment with C—E—C (E= Si, Ge) angles in the range 104.47 (5)–114.67 (5)°. The molecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring molecules are combined to dimers by six T-shaped C—H...π interactions, forming sixfold phenyl embraces (6PE).