Published in
Royal Society of Chemistry, Polymer Chemistry, 4(7), p. 933-939
DOI: 10.1039/c5py01855b
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SET-LRP of NIPAM in water via in situ reduction of Cu(ii) to Cu(0) with NaBH4
Journal article published in 2016 by
Mikhail Gavrilov,
Timothy J. Zerk,
Paul V. Bernhardt,
Virgil Percec,
Michael J. Monteiro 
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Abstract
The direct and quantitative reduction of the air-stable Cu(ii)Br2/Me6TREN to Cu(0) by NaBH4 represents a new method for the aqueous single electron transfer-living radical polymerization (SET-LRP) of water soluble polymers.