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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 20(16), p. 9220-9228, 2014

DOI: 10.1039/c4cp00711e

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Combining experiment and theory to elucidate the role of supercritical water in sulfide decomposition

Journal article published in 2014 by Yuko Kida, Caleb A. Class ORCID, Anthony J. Concepcion, Michael T. Timko, William H. Green
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Supercritical water is observed to react with alkyl sulfides, forming H2S, CO, and alkanes. Quantum chemistry calculations show this occurs via a multistep mechanism involving both free radical and pericyclic reactions, with water acting as both a reagent and a catalyst.