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Wiley, Macromolecular Rapid Communications, 23(32), p. 1921-1924, 2011

DOI: 10.1002/marc.201100477

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Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

Journal article published in 2011 by Nicolas Popoff, Jeff Espinas, Eric Gouré, Olivier Boyron, Erwan Le Roux, Erwan Le Roux, Jean-Marie Basset ORCID, Régis M. Gauvin, Aimery De Mallmann, Mostafa Taoufik
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This paper is available in a repository.

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Abstract

Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.