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MDPI, Magnetochemistry, 1(2), p. 9, 2016

DOI: 10.3390/magnetochemistry2010009

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A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

Journal article published in 2016 by Helena J. Shepherd, George Tonge, Lauren Hatcher, Mathew Bryant ORCID, Jane Knichal, Paul Raithby, Malcolm Halcrow ORCID, Rafal Kulmaczewski ORCID, Kevin Gagnon, Simon Teat
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.