The potential of retrieving the bottom layer snow density and soil permittivity under dry snow cover conditions from L-band passive microwave observations was analyzed using multi-angular brightness temperatures measured at horizontal and vertical polarization over two test sites in northern Finland. The near-continuous time series of L-band brightness temperatures covers a total of six winter seasons, over both dry mineral soil in a forest clearing, and organic soil over a wetland site. Detailed measurements of snow and soil conditions are available from both sites. Complementing a previous theoretical study, we show that dry snow cover influences the observed L-band brightness temperatures as a result of both impedance matching and changes in the refraction angle at the snow–soil interface. Exploiting these effects, we demonstrate the retrieval of the bottom layer snow density and the influence of dry snow cover on simultaneously retrieved soil permittivity — a consideration which is currently not accounted for in Soil Moisture and Ocean Salinity (SMOS) retrievals of soil permittivity in the presence of dry snow. Depending on season, the mean bias error between retrieved and in situ snow density measured in the lower snow layers was between − 6 kg m− 3 and 15 kg m− 3 for the forest clearing site, and between 37 kg m− 3 and 90 kg m− 3 for the wetland site, demonstrating the feasibility of the retrieval approach at the plot scale. In winter conditions, the ground permittivity retrieved without considering the impact of dry snow on L-band emission was, on average, 35% lower for both test sites, which indicates possible errors in current SMOS ground permittivity retrievals under dry snow conditions. The application of SMOS data to simultaneously retrieve dry snow density and ground permittivity is a complex task due to heterogeneous land cover and snow/soil conditions within SMOS pixels (≈ 45 km resolution). An approach that considers land cover variations and the spatial variability of snow cover is required to fully determine the feasibility of the methodology to aid e.g. improving estimates snow water equivalent from other sensors, and to take into account effects of dry snow in SMOS-based retrievals of ground permittivities. The results should also be applicable to other L-band sensors in space, such as the recently launched NASA Soil Moisture Active Passive (SMAP) mission.