Published in

European Geosciences Union, Atmospheric Measurement Techniques, 2(6), p. 371-386, 2013

DOI: 10.5194/amt-6-371-2013

European Geosciences Union, Atmospheric Measurement Techniques Discussions, 5(5), p. 7095-7139

DOI: 10.5194/amtd-5-7095-2012

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Characterisation of GOME-2 formaldehyde retrieval sensitivity

Journal article published in 2012 by W. Hewson, H. Boesch ORCID, H. Bösch, M. P. Barkley, I. De Smedt ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Data provided by SHERPA/RoMEO

Abstract

Formaldehyde (CH 2 O) is an important tracer of tropospheric photochemistry, whose slant column abun-dance can be retrieved from satellite measurements of solar backscattered UV radiation, using differential absorption re-trieval techniques. In this work a spectral fitting sensitivity analysis is conducted on CH 2 O slant columns retrieved from the Global Ozone Monitoring Experiment 2 (GOME-2) in-strument. Despite quite different spectral fitting approaches, the retrieved CH 2 O slant columns have geographic distribu-tions that generally match expected CH 2 O sources, though the slant column magnitudes and corresponding uncertainties are particularly sensitive to the retrieval set-up. The choice of spectral fitting window, polynomial order, I 0 correction, and inclusion of minor absorbers tend to result in the largest mod-ulations of retrieved slant column magnitude and fit qual-ity. However, application of a reference sector correction us-ing observations over the remote Pacific Ocean is shown to largely homogenise the resulting CH 2 O vertical columns ob-tained with different retrieval settings, thereby largely reduc-ing any systematic error sources from spectral fitting.