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American Physical Society, Physical Review Letters, 24(86), p. 5514-5517, 2001

DOI: 10.1103/physrevlett.86.5514

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Absence of an Abrupt Phase Change from Polycrystalline to Amorphous in Silicon with Deposition Temperature

Journal article published in 2001 by J. E. Gerbi, P. M. Voyles ORCID, J. R. Abelson, J. M. Gibson, M. M. J. Treacy
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Using fluctuation electron microscopy, we have observed an increase in the mesoscopic spatial fluctuations in the diffracted intensity from vapor-deposited silicon thin films as a function of substrate temperature from the amorphous to polycrystalline regimes. We interpret this increase as an increase in paracrystalline medium-range order in the sample. A paracrystal consists of topologically crystalline grains in a disordered matrix; in this model the increase in ordering is caused by an increase in the grain size or density. Our observations are counter to the previous belief that the amorphous to polycrystalline transition is a discontinuous disorder-order phase transition.