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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 13(16), p. 6139, 2014

DOI: 10.1039/c3cp54896a

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Outer Co(II) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Outer Co(ii) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.