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American Chemical Society, Inorganic Chemistry, 7(39), p. 1602-1605, 2000

DOI: 10.1021/ic9909678

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A Linear, Four-Spin Mn(II)−Nitronyl−Nitroxide-Substituted Phosphine Oxide System Exhibiting Both Antiferro- and Ferromagnetic Interactions§

Journal article published in 2000 by Corinne Rancurel, Daniel B. Leznoff, Jean-Pascal Sutter ORCID, Philippe Guionneau, Daniel Chasseau, Janis Kliava, Olivier Kahn
This paper is available in a repository.
This paper is available in a repository.

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Abstract

{[oPONit]MnCl(mu-Cl)}(2) is a di-chloro-bridged Mn(II) binuclear compound in which each Mn(II) is coordinated by (o-nitronyl nitroxide-phenyl)diphenylphosphine oxide acting as a bidentate ligand via the oxygen atoms of the P=O and N-O groups. The spectrum of the low-lying states has been deduced from the magnetic and EPR properties. Antiferromagnetic Mn-radical and ferromagnetic Mn-Mn interactions lead to a S = 4 ground state.