Published in

Royal Society of Chemistry, RSC Advances, 23(5), p. 18067-18074, 2015

DOI: 10.1039/c4ra16954a

Links

Tools

Export citation

Search in Google Scholar

A meta-molecular tailoring strategy towards an efficient violet-blue organic electroluminescent material

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Red circle
Preprint: archiving forbidden
Green circle
Postprint: archiving allowed
Green circle
Published version: archiving allowed
Data provided by SHERPA/RoMEO

Abstract

In this paper, an efficient violet-blue emitter 4,4''-bis(1-(4-(tert-butyl)phenyl)-1H-phenanthro [9,10-d]imidazol-2-yl)-1,1':3',1''-terphenyl (m-BBTPI) was designed and synthesized by linking two phenanthroimidazole units via the meta position of a freely rotatable phenyl bridge. The present design provides a suitable level of conjugation between the two phenanthroimidazole units such that fluorescence is strengthened over the single unit while a violet-blue emission can be maintained by limiting the amount of redshift. The new emitter m-BBTPI is also found to have good thermal stability, strong violet-blue emission and bipolar charge transporting properties. An electroluminescent device using m-BBTPI as a non-doped emission layer shows a low turn-on voltage (3.2 V), good colour purity (0.16, 0.06) as well as high current and power efficiencies (1.99 cd A-1, 1.81 lm W-1). These performance parameters are comparable to the state-of-the-art non-doped violet-blue OLEDs.