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Royal Society of Chemistry, Chemical Communications, 14(51), p. 2972-2975

DOI: 10.1039/c4cc09986a

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Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67

Journal article published in 2015 by William Salomon, Catherine Roch-Marchal, Pierre Mialane, Paul Rouschmeyer, Christian Serre, Mohamed Haouas ORCID, Francis Taulelle, Shu Yang, Laurent Ruhlmann, Anne Dolbecq
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The encapsulation of polyoxometalates within the large pores of the Zr(iv) biphenyldicarboxylate UiO-67 metal-organic framework has been achieved, for the first time, by direct solvothermal synthesis. The resulting POM@UiO-67 composite materials were fully characterized by XRPD, IR, MAS NMR, N2 porosimetry measurements and cyclic voltammetry.