Published in
Royal Society of Chemistry, Chemical Communications, 15(51), p. 3243-3246
DOI: 10.1039/c4cc08471c
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On-surface self-organization of a robust metal–organic cluster based on copper(I) with chloride and organosulphur ligands
Journal article published in 2015 by
Gonzalo Otero-Irurueta,
Irene Hernández-Rodríguez,
Jóse I. Martínez 
,
Rogger Palacios-Rivera ,
Francisco J. Palomares,
Maria F. López,
Almudena I. Gallego,
Salome Delgado,
Félix Zamora ,
Javier Mendez,
Jóse A. Martin Gago
,
Rogger Palacios-Rivera ,
Francisco J. Palomares,
Maria F. López,
Almudena I. Gallego,
Salome Delgado,
Félix Zamora ,
Javier Mendez,
Jóse A. Martin Gago
This paper is available in a repository.
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Abstract
Direct sublimation of a Cu4Cl4 metal-organic cluster on Cu(110) in ultra-high vacuum allows the formation of ultra-large well-organized metal-organic supramolecular wires. Our results show that the large monomers assemble to each other by π−π interactions connecting dipyrimidine units and are stabilized by the surface.