Elsevier, Coordination Chemistry Reviews, (299), p. 1-21, 2015
DOI: 10.1016/j.ccr.2015.03.024
Full text: Unavailable
We review the past and current efforts towards interesting molecular, magnetic systems encompassing inter-metallic fluoride bridging. The efficacy of fluoride as mediator of magnetic interactions is addressed and the use of the structure-directing properties of the fluoride ion as a synthetic handle for polymetallic systems is established. Finally, the magnetic properties of selected examples of systems of increasing complexity are discussed.