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World Scientific Publishing, Journal of Porphyrins and Phthalocyanines, 03(17), p. 165-196

DOI: 10.1142/s1088424613300012

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New developments in chemistry of organometallic porphyrins and their analogs

Journal article published in 2013 by Andrea Vecchi, Pierluca Galloni ORCID, Barbara Floris, Victor N. Nemykin
This paper is available in a repository.
This paper is available in a repository.

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Abstract

In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or β-pyrrolic position; or (iii) β,β′-fused into the aromatic system as well as porphyrinoids with organometallic fragments σ-bonded in η1-fashion were overviewed.