World Scientific Publishing, Journal of Porphyrins and Phthalocyanines, 03(17), p. 165-196
DOI: 10.1142/s1088424613300012
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In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or β-pyrrolic position; or (iii) β,β′-fused into the aromatic system as well as porphyrinoids with organometallic fragments σ-bonded in η1-fashion were overviewed.