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American Chemical Society, ACS Catalysis, 11(2), p. 2242-2246, 2012

DOI: 10.1021/cs300445y

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Redox-Controlled Crotyl Alcohol Selective Oxidation: In Situ Oxidation and Reduction Dynamics of Catalytic Pd Nanoparticles via Synchronous XANES/MS

Journal article published in 2012 by Christine V. Gaskell, Christopher M. A. Parlett, Mark A. Newton, Karen Wilson ORCID, Adam F. Lee
This paper is available in a repository.
This paper is available in a repository.

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Abstract

In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.